One has twice the number of strands as the other (i.e. 14 strands of 0.2 wire as opposed to 7). The 14 strand will have a lower resistance/metre than the 7, so for long runs it would be better. However, being a security system I doubt you are dealing with high currents, so voltage drop probably won't be a big issue.
Does the system manual stipulate what size cable should be used?
Is there a substantial difference in price?