Nev,
once you've got the ground levelled, either by hand or machine you'll need to build some profiles at each corner and square and level up for your formwork. You'll need to borrow/buy/hire a screed, bull float, small mag float and a steel trowel as well as an edger. If the slab is large enough you may want a helicopter (steel trowelling machine). While placing and finishing concrete is simple in theory, in practice there's quite an art to it. I've done small slabs (up to 30M2) but when I did my shed (10 x 7.5) I did all the prep work and got a concretor in to place and finish it.
Mick