Hi Darren
I'd say insulate with batts, the ideal time, slip them onto the battens just before you fix your ceiling. Never going to be as easy again.
I painted my old Zincalume roof with standard white "weathershield", if its white it's heat reflective, no primer. 2 coats. Done it a couple of times over the last ten years.
Last time I used a kitchen broom to brush it on. Saves hire of spray gun and wasted paint, and saves your back. Those corrugated foam rollers are useless.
I'd say the best thing is a couple of 300mm whirlybirds as high up as possible, and maybe a few eaves vents if necessary.
Not one single thing does the complete job, it's a combination I guess.
Cheers
Bill (in Darwin)