Done something similar on a bigger sized shed with 4.2m high walls.
The spanning of rafters like you describe will be fine so long as they are sized correctly.
How high are the current shed walls?
Assume the water we see is the result of you hosing it out and not dampness?
Is the slab infilled so it virtually seals the tin sides to the concrete? or is the tin sitting on top of the slab or partway down the side of the slab?
Do you know if the slab had a plastic membrane before the pour?....possibly easy to find out if you dig a small hole on the outside of the shed
....just something to consider for possible future dampness issues, may need to consider base plate options (others here will know better than I)
The walls could easily be 90x35mm @ 450 centres as you planed but nothing wrong with 90x45. Just staple the siso foil to the back side of the frame before standing the frames up.
The ceiling rafters and walls aren't really holding a lot of weight (10mm plaster board) which simply needs the correct size for the span and the 10mm plaster board. One thing to consider is will you use the crawl space as a small storage area keeping in mind it will be as hot as hell!!! If so, factor what sort of weight and place some 12mm ply or yellow tongue flooring in strategic areas....even a 400m strip down the length in case you ever have to crawl up in that tight space will make it really easy Suggest to buy a roll or packing tape, after you run the lighting wiring, staple this to the underside approx 450mm apart, stack in your insulation b4 you fix the plaster https://www.ebay.com.au/itm/37158443...79f073bc69c5cb
If you stick R2 in walls and R4 or R6 in the ceiling, you will be amazed at just how cool it is in a "shed" as the walls wont hold the heat with this type of construction (will flow up into the ceiling). If you can rig up you ceiling so the heat escapes easily, its likely to be cooler than you house!!!....that been my experience however with mine its 4.2m high walls with a mezzanine so slightly different.
If you're after an additional 100/200mm usable width, just set back your stud walls exposing the single side post and butt your plaster up each side.
There are 2 other construction methods to consider that will be a lot cheaper but different finish result and not as well insulated in the roof.
1. Roof: Just fix 6mm or 9mm ply to the roof. Use cement joiners to butt the joins to each other. Ive not done this method, but others here have and appears to look quite good.
2. Walls: Screw yellow tongue flooring directly to the wall tophats with 5 to 10mm packers on the bottom to keep it off the slab. Could seal the bottom edge for better dampness protection. Ive seen 3 sheds done this way and the finish looks really great, just paint your preferred color. You will still get R2 batts into the walls.